MEASUREMENT OF THERMOPHYSICAL PROPERTIES OF AMMONIUM-SALTS IN THE SOLID AND MOLTEN STATES

Citation
Mbs. Osman et al., MEASUREMENT OF THERMOPHYSICAL PROPERTIES OF AMMONIUM-SALTS IN THE SOLID AND MOLTEN STATES, Journal of thermal analysis, 46(6), 1996, pp. 1697-1703
Citations number
5
Categorie Soggetti
Chemistry Analytical
Journal title
ISSN journal
03684466
Volume
46
Issue
6
Year of publication
1996
Pages
1697 - 1703
Database
ISI
SICI code
0368-4466(1996)46:6<1697:MOTPOA>2.0.ZU;2-L
Abstract
The thermal conductivity, specific heat capacity and thermal diffusivi ty of solid and molten ammonium thiocyanate, ammonium formate, ammoniu m acetate and ammonium nitrate were measured in the temperature range 80-190 degrees C, including the solid and liquid phases, by using the AC-heated strip (wire) technique. The results indicate that the therma l conductivities depend on the type of the ammonium salt. It was found that the mechanism of heat transfer is due to phonons in the region b elow the melting points of the salts, while above this region the main mechanism is due to conduction.