PALLADIUM-CATALYZED CONVERSION OF VINYL BROMO ALLYLIC ALCOHOLS INTO VINYLIC CARBONYL-COMPOUNDS AND OXIDATION OF SECONDARY ALCOHOLS TO KETONES

Authors
PITRE SV VANKAR PS VANKAR YD
Citation
Sv. Pitre et al., PALLADIUM-CATALYZED CONVERSION OF VINYL BROMO ALLYLIC ALCOHOLS INTO VINYLIC CARBONYL-COMPOUNDS AND OXIDATION OF SECONDARY ALCOHOLS TO KETONES, Tetrahedron, 52(37), 1996, pp. 12291-12298
Citations number
25
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Tetrahedron → ACNP
ISSN journal
00404020
Volume
52
Issue
37
Year of publication
1996
Pages
12291 - 12298
Database
ISI
SICI code
0040-4020(1996)52:37<12291:PCOVBA>2.0.ZU;2-F
Abstract
A variety of vinyl bromo allylic alcohols are converted into the corre sponding vinylio carbonyl compounds and secondary alcohols are oxidise d into ketones upon treatment with palladium acetate in the presence o f potassium carbonate under the typical Heck reaction conditions. Copy right (C) 1996 Elsevier Science Ltd