TETRAMETHYLETHYLENE DIAMINE TRIMETHYLSILYL CHLORIDE MEDIATED ADDITIONOF BENZYL COPPER REAGENTS TO ALPHA,BETA-UNSATURATED ESTERS

Authors
VANHEERDEN PS BEZUIDENHOUDT BCB FERREIRA D
Citation
Ps. Vanheerden et al., TETRAMETHYLETHYLENE DIAMINE TRIMETHYLSILYL CHLORIDE MEDIATED ADDITIONOF BENZYL COPPER REAGENTS TO ALPHA,BETA-UNSATURATED ESTERS, Tetrahedron, 52(37), 1996, pp. 12313-12322
Citations number
34
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Tetrahedron → ACNP
ISSN journal
00404020
Volume
52
Issue
37
Year of publication
1996
Pages
12313 - 12322
Database
ISI
SICI code
0040-4020(1996)52:37<12313:TDTCMA>2.0.ZU;2-X
Abstract
Several benzylic copper reagents, benzylcopper, 4-methoxybenzylcopper and 1-phenylethylcopper, facilitate the conjugate addition of the corr esponding benzyl ligands to alpha,beta-enoates in the presence of tetr amethylethylene diamine and trimethylsilyl chloride in high yields. Co pyright (C) 1996 Published by Elsevier Science Ltd