I. Rochester et al., EFFECTIVE NITRIFICATION INHIBITORS MAY IMPROVE FERTILIZER RECOVERY INIRRIGATED COTTON, Biology and fertility of soils, 23(1), 1996, pp. 1-6
N fertilizer is often poorly recovered in irrigated cotton production,
due to N loss through denitrification. We researched the ability of i
nhibitors to delay nitrification and reduce the availability of NO; to
denitrifying microorganisms and thus improve N fertilizer recovery. 2
-Ethynylpyridine, etridiazole, and nitrapyrin proved highly effective
nitrification inhibitors, although nitrification was evident several w
eeks after their application. CaC2 was relatively ineffective, even wh
en wax-coated to prolong the evolution of C2H2. Phenylacetylene and et
hynylcyclohexanol were also ineffective, despite having a chemical str
ucture similar to 2-ethynylpyridine. A strong association was identifi
ed between each compound's ability to inhibit nitrification and its ca
pacity to improve N fertilizer recovery. In one experiment, N fertiliz
er recovery was increased by similar to 50% with 2-ethynylpyridine, et
ridiazole, or nitrapyrin application, from 33% without inhibitors. The
inhibitors had little effect on fertilizer recovery where N losses we
re relatively small. 3-Methyl pyrazole significantly increased N uptak
e and lint yield, but the nitrification inhibitors had no significant
effect on N uptake or on yield in two of the three of the cotton crops
. A laboratory study confirmed that nitrification inhibitor effectiven
ess declined in the order 2-ethynylpyridine>etridiazole>nitrapyrin>3-m
ethyl pyrazole>phenylacetylene>CaC2>ethynylcyclohexanol.