K. Niwase et al., GENERATION OF NANOSIZED GROOVES AND HOLES ON METAL-SURFACES BY LOW-TEMPERATURE ELECTRON-IRRADIATION, Philosophical magazine letters, 74(3), 1996, pp. 167-174
This paper reports a novel phenomenon in surface physics, namely the f
ormation of aligned nanogrooves and deep nanoholes on the exit surface
of thin (001) gold foils irradiated with high doses of 360, 800 and 1
250 keV electrons at temperatures of about 100 K. The grooves and hole
s, with widths between about 1 and 2 nm, appear to be the smallest so
far produced in metals. The formation of the nanogrooves depends on th
e irradiation direction: irradiation along [001] produces grooves exte
nding along [100] and [010], irradiation along [011] gives grooves alo
ng [100], whereas no marked grooves have been observed for [111] irrad
iations. By contrast, nanoholes, which may reach depths exceeding 20 n
m, develop mainly along the beam direction. At room temperature the na
noholes transform into voids of larger diameters. There is strong evid
ence that the formation of the groove pattern is a self-organized proc
ess. A tentative mechanism involving symmetry breaking by strongly ani
sotropic surface collision sequences is proposed.