THE APPLICATION OF THE FORMYL C-H--O HYDROGEN-BOND POSTULATE TO THE UNDERSTANDING OF ENANTIOSELECTIVE REACTIONS INVOLVING CHIRAL BORON LEWIS-ACIDS AND ALDEHYDES

Authors
COREY EJ ROHDE JJ
Citation
Ej. Corey et Jj. Rohde, THE APPLICATION OF THE FORMYL C-H--O HYDROGEN-BOND POSTULATE TO THE UNDERSTANDING OF ENANTIOSELECTIVE REACTIONS INVOLVING CHIRAL BORON LEWIS-ACIDS AND ALDEHYDES, Tetrahedron letters, 38(1), 1997, pp. 37-40
Citations number
10
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Tetrahedron letters → ACNP
ISSN journal
00404039
Volume
38
Issue
1
Year of publication
1997
Pages
37 - 40
Database
ISI
SICI code
0040-4039(1997)38:1<37:TAOTFC>2.0.ZU;2-0
Abstract
A number of noteworthy enantioselective reactions involving a variety of chiral boron Lewis acids and aldehydes can be rationalized in terms of the occurrence of formyl CH-O hydrogen bonds in the transition sta tes and the additional three-dimensional organization which they provi de. Copyright (C) 1996 Elsevier Science Ltd