DMF AS A DIMETHYLAMINE EQUIVALENT IN THE PALLADIUM-CATALYZED NUCLEOPHILIC-SUBSTITUTION OF NAPHTHYLMETHYL AND ALLYL ACETATES

Authors
TOFFANO M LEGROS JY FIAUD JC
Citation
M. Toffano et al., DMF AS A DIMETHYLAMINE EQUIVALENT IN THE PALLADIUM-CATALYZED NUCLEOPHILIC-SUBSTITUTION OF NAPHTHYLMETHYL AND ALLYL ACETATES, Tetrahedron letters, 38(1), 1997, pp. 77-80
Citations number
19
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Tetrahedron letters → ACNP
ISSN journal
00404039
Volume
38
Issue
1
Year of publication
1997
Pages
77 - 80
Database
ISI
SICI code
0040-4039(1997)38:1<77:DAADEI>2.0.ZU;2-C
Abstract
Naphthylmethyl acetates 1a and 2a were substituted by morpholine in DM PU in the presence of 2 mol% of [Pd(dba)(2) + 15 dppe] to give product s 9-10 in 66-70% isolated yield. In DMF in the presence of benzylamine , N,N-dimethylnaphthylmethylamines 11-12 were produced in 78-85% isola ted yield. Copyright (C) 1996 Elsevier Science Ltd