CHEMISTRY OF DIMETHYLAMINOMETHYLPORPHYRINS .2. PORPHYRIN DIMERS LINKED BY PYRROLYLMETHYLENE UNITS

Citation
Dv. Yashunsky et al., CHEMISTRY OF DIMETHYLAMINOMETHYLPORPHYRINS .2. PORPHYRIN DIMERS LINKED BY PYRROLYLMETHYLENE UNITS, Tetrahedron letters, 38(1), 1997, pp. 105-108
Citations number
5
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
ISSN journal
00404039
Volume
38
Issue
1
Year of publication
1997
Pages
105 - 108
Database
ISI
SICI code
0040-4039(1997)38:1<105:COD.PD>2.0.ZU;2-D
Abstract
Reaction of various a-unsubstituted pyrrole derivatives with trimethyl (porphyrinylmethyl)-ammonium iodides (generated in situ from the corre sponding meso-dimethylaminomethylporphyrins and iodomethane) afforded a number of symmetrical and unsymmetrical porphyrinylmethylpyrrole add ucts, including dimers linked by one and two pyrrolylmethylene units. The NMR spectra of the monopyrrole-linked dimers indicate a preference for a face-to-face conformation. Copyright (C) 1996 Elsevier Science Ltd