ON NABA3RUO6 AND NABA3IRO6 - 2 NOBLE-META L OXOMETALLATES SHOWING SR4PTO6 STRUCTURE

Citation
S. Frenzen et H. Mullerbuschbaum, ON NABA3RUO6 AND NABA3IRO6 - 2 NOBLE-META L OXOMETALLATES SHOWING SR4PTO6 STRUCTURE, Zeitschrift fur Naturforschung. B, A journal of chemical sciences, 51(8), 1996, pp. 1204-1206
Citations number
17
Categorie Soggetti
Chemistry Inorganic & Nuclear","Chemistry Inorganic & Nuclear
ISSN journal
09320776
Volume
51
Issue
8
Year of publication
1996
Pages
1204 - 1206
Database
ISI
SICI code
0932-0776(1996)51:8<1204:ONAN-2>2.0.ZU;2-U
Abstract
Single crystals of NaBa3RuO6 (I) and NaBa3IrO6 (II) have been prepared by crystallization from melts in closed silver tubes. The crystal str uctures were investigated by X-ray techniques. Both compounds crystall ize with trigonal (rhombohedral) symmetry, space group D-3d(6) -R (3) over bar c, I: a = 10.107(2), c = 11.872(2) Angstrom, II: a = 10.128(2 ), c = 11.905(2) Angstrom Z = 6. I and II are isostructural to the Sr4 PtO6 type.