The energy spectrum of a hole in the valence bands of a Xe crystal whi
ch is bound to a negative point charge, is calculated and analyzed in
form of a correlation diagram relating the individual bands of the val
ence band structure to the level scheme of the bound hole states. It i
s found that this energy spectrum depends critically on the whole band
structure, and in particular on the splitting of the j = 3/2 bands. O
ur calculated binding energies are in good agreement with recent exper
imental results. (C) 1996 American Institute of Physics.