STEREOSELECTIVE SYNTHESIS OF 11Z-RETINAL BY USE OF TRICARBONYLIRON COMPLEX

Authors
WADA A TANAKA Y FUJIOKA N ITO M
Citation
A. Wada et al., STEREOSELECTIVE SYNTHESIS OF 11Z-RETINAL BY USE OF TRICARBONYLIRON COMPLEX, Bioorganic & medicinal chemistry letters, 6(17), 1996, pp. 2049-2052
Citations number
13
Categorie Soggetti
Chemistry Inorganic & Nuclear","Chemistry Medicinal
Journal title
Bioorganic & medicinal chemistry letters → ACNP
ISSN journal
0960894X
Volume
6
Issue
17
Year of publication
1996
Pages
2049 - 2052
Database
ISI
SICI code
0960-894X(1996)6:17<2049:SSO1BU>2.0.ZU;2-4
Abstract
Peterson reaction of 7E,9E-beta-ionylideneacetaldehyde-tricarbonyliron complex with ethyl trimethylsilyl acetate afforded Z-olefin in high s tereoselectivity, which was converted to the corresponding 11Z-retinal in excellent yield. Copyright (C) 1996 Elsevier Science Ltd