Ar. Yen et al., THE INFLUENCE OF MGO MG AND AL2O3/AL ADDITIVES ON COERCIVITY, THERMAL-STABILITY, AND MICROSTRUCTURE OF ND-FE-B MAGNETS/, Materials research bulletin, 31(10), 1996, pp. 1171-1177
The influence of MgO/Mg and Al2O3/Al addition on the coercivity, therm
al stability, and microstructure of Nd22Fe71B7 magnets has been invest
igated. It has been found that (1) the coercivity is considerably enha
nced by the addition of MgO, Al2O3, Mg, and Al; and (2) the thermal st
ability can be improved by the MgO, Al2O3, Mg, and Al additives, espec
ially MgO and Al2O3. Microstructural studies reveal that two different
intergranular phases appear in the oxide- and pure-element-doped magn
ets. The modification of the properties can be attributed to the appea
rance of the phases. It is further found that the introduction of an a
ppropriate amounts of oxygen together with Mg or Al is beneficial for
the coercivity and thermal stability of Nd-Fe B magnets, and the alloy
ing to the intergranular regions (the alloying elements are introduced
into intergranular regions) may be a more effective approach to impro
ve the properties of magnets.