The residual stress in epitaxial InP on (001) Si was investigated by p
hotoreflectance spectroscopy. Depending on doping concentration, low-f
ield and intermediate-field spectra were measured which were quantitat
ively analysed by a third-derivative approximation or by a multilayer
model, respectively. In both cases, transitions only from the heavy-ho
le and the split-off valence subbands into the conduction band contrib
uted to the spectra, while the light-hole to conduction-band transitio
n was absent. In addition to the energy shift due to tensile strain ca
used by the different thermal expansion coefficients of InP and Si, a
signal component originating from compressive strain in the InP was ob
served. This effect is attributed to the clustering of dislocations at
twin defects. As a result, a model of the defect distribution in the
heteroepitaxial InP layers was presented.