Radiative recombination mechanisms in n-GaSe doped with Sn have been i
nvestigated through photoluminescence (PL) measurements. For samples d
oped from 0.1 to 0.5 at.%, the PL spectra at 77 K are dominated by the
emission band at 1.29 eV. The temperature dependences of the PL inten
sity, peak energy and full width at half-maximum are characterized usi
ng the configuration coordinate model. The 1.29 eV band is associated
with the donor-vacancy complex center.