BELOW BAND-GAP IR RESPONSE OF SUBSTRATE-FREE GAAS SOLAR-CELLS USING 2-PHOTON UP-CONVERSION

We have developed a device based upon the concept of two-photon up-con version to use a part of the IR photons otherwise lost by transparency in a GaAs cell. An ultra thin GaAs cell has been fabricated using the technique of epitaxial lift-off (ELO). This thin cell is placed on to p of a 100 mu m thick vitroceramic doped with Yb3+ and Er3+. The two p hoton upconversion process involved here is based on sequential absorp tion and energy transfer of two IR photons from Yb3+ to Er3+; which th en emit one photon in the green. This green light then produces a phot oresponse in the GaAs cell. This cell coupled to the vitroceramic was lighted by an Ti-sapphire IR laser at 1.391 eV, a photon energy below the band gap of GaAs, with an input power able to reach similar to 1 W . The GaAs cell photoresponse increases quadratically with the input e xcitation. For an input excitation of 1 W at 1.39 eV on a 0.039 cm(2) substrate-free GaAs cell, the measured efficiency was 2.5%.