NEW ORGANIC METALS - RADICAL-CATION SALTS OF BIS(ETHYLENEDIOXO)TETRATHIAFULVALENE WITH HALIDE MERCURATE ANIONS

Citation
Ei. Zhilyaeva et al., NEW ORGANIC METALS - RADICAL-CATION SALTS OF BIS(ETHYLENEDIOXO)TETRATHIAFULVALENE WITH HALIDE MERCURATE ANIONS, Russian chemical bulletin, 45(5), 1996, pp. 1107-1110
Citations number
16
Categorie Soggetti
Chemistry
Journal title
ISSN journal
10665285
Volume
45
Issue
5
Year of publication
1996
Pages
1107 - 1110
Database
ISI
SICI code
1066-5285(1996)45:5<1107:NOM-RS>2.0.ZU;2-K
Abstract
Radical cation salts with halide mercurate anions were obtained by the electrochemical oxidation of bis(ethylenedioxo)tetrathiafulvalene (BE DO-TTF), and their conductivity was studied. The compounds (BEDO-TTF)( 4)Hg(3)X(8) (X = Cl or Pr), (BEDO-TTF)(4)Hg3.5I9, and (BEDO-TTF)(2)HgB r3 possess the conductivity of the metallic type down to helium temper atures.