INTERMOLECULAR INTERACTIONS OF TETRAANIONS OF MACROCYCLIC TETRARESORCINOL IN H2O-DMF SOLUTIONS

Authors
MUSTAFINA AR GALIMOV RR ERMOLAEVA LV SARVAROVA NN BURILOV AR REZNIK VS
Citation
Ar. Mustafina et al., INTERMOLECULAR INTERACTIONS OF TETRAANIONS OF MACROCYCLIC TETRARESORCINOL IN H2O-DMF SOLUTIONS, Russian chemical bulletin, 45(5), 1996, pp. 1111-1114
Citations number
11
Categorie Soggetti
Chemistry
Journal title
Russian chemical bulletin → ACNP
ISSN journal
10665285
Volume
45
Issue
5
Year of publication
1996
Pages
1111 - 1114
Database
ISI
SICI code
1066-5285(1996)45:5<1111:IIOTOM>2.0.ZU;2-C
Abstract
According to the data of pH-metric titration, macrocyclic tetraresorci nol (1c) dissociates stepwise with the abstraction of one, two, and fo ur protons. Aggregation of tetraanions of 1c in H2O-DMF solutions was detected by conductometry. The degree of aggregation increases as the size of the counterion decreases and the content of DMF in the solvent mixture increases.