DIELECTRIC-RELAXATION OF BINARY-MIXTURES OF 3 ALCOHOLS WITH DIMETHYLFORMAMIDE

Authors
STOCKHAUSEN M BUSCH H
Citation
M. Stockhausen et H. Busch, DIELECTRIC-RELAXATION OF BINARY-MIXTURES OF 3 ALCOHOLS WITH DIMETHYLFORMAMIDE, Physics and chemistry of liquids, 32(3), 1996, pp. 183-189
Citations number
10
Categorie Soggetti
Chemistry Physical","Physics, Condensed Matter
Journal title
Physics and chemistry of liquids → ACNP
ISSN journal
00319104
Volume
32
Issue
3
Year of publication
1996
Pages
183 - 189
Database
ISI
SICI code
0031-9104(1996)32:3<183:DOBO3A>2.0.ZU;2-P
Abstract
The dielectric spectra of binary liquid mixtures of the following alco hols with N,N-dimethylformamide (DMFA) have been measured between 5 MH z and 72 GHz at 20 degrees C:1-Hexanol, 1,2-hexanediol and 1,4-butaned iol. The analysis of the spectra, which is particularly aimed at infor mation on hetero-association, gives evidence for the formation of mixe d aggregations, indicated by a minimum in the 'free' DMFA relaxation c ontribution at a mixture ratio of about 1:1 for hexanol/DMFA and about 1:2 in case of the dihydric alcohol/DMFA systems.