CATHODIC INCORPORATION OF LITHIUM INTO PRODUCTS OF THE PARTIAL ELECTROREDUCTION OF COPPER IONS

Authors
IVANOVA ND FILATOV KV FILATOV AV BOLDYREV EI
Citation
Nd. Ivanova et al., CATHODIC INCORPORATION OF LITHIUM INTO PRODUCTS OF THE PARTIAL ELECTROREDUCTION OF COPPER IONS, Russian journal of electrochemistry, 32(8), 1996, pp. 854-857
Citations number
11
Categorie Soggetti
Electrochemistry
Journal title
Russian journal of electrochemistry → ACNP
ISSN journal
10231935
Volume
32
Issue
8
Year of publication
1996
Pages
854 - 857
Database
ISI
SICI code
1023-1935(1996)32:8<854:CIOLIP>2.0.ZU;2-D
Abstract
The correlation between the physical and electrochemical properties of products of the partial reduction of copper ions is studied. The prod ucts represent a heterogeneous system containing the copper metal and oxide-hydroxide compounds of Cu(I) of nonstoichiometric composition. L ithium ions are found to be more mobile in copper oxides of nonstoichi ometric composition, compared with stoichiometric oxides. It is shown that the deviation of oxide composition from stoichiometry and the rat e of mass transfer can be purposefully varied by the conditions under which the compound is electrochemically synthesized.