STANNYLENE INSERTION INTO AN AMINO-STABILIZED IRON-SILYLENE COMPLEX -SYNTHESIS OF O)P)FE([NME(2)SI(OR)(2)(SNNBU(T)SIME(2)NHBU(T))])] (R=ME, ET)

Authors
BRAUNSTEIN P HUCH V STERN C VEITH M
Citation
P. Braunstein et al., STANNYLENE INSERTION INTO AN AMINO-STABILIZED IRON-SILYLENE COMPLEX -SYNTHESIS OF O)P)FE([NME(2)SI(OR)(2)(SNNBU(T)SIME(2)NHBU(T))])] (R=ME, ET), Chemical communications, (17), 1996, pp. 2041-2042
Citations number
19
Categorie Soggetti
Chemistry
Journal title
Chemical communications → ACNP
ISSN journal
13597345
Issue
17
Year of publication
1996
Pages
2041 - 2042
Database
ISI
SICI code
1359-7345(1996):17<2041:SIIAAI>2.0.ZU;2-N
Abstract
Reaction of the HNMe(2)-stabilized iron-silylene complexes (1a,b) with the stannylene reagent SnNBu(t)SiMe(2)NBu(t) 2 occurs selectively by insertion into the N-H bond to give novel types of base-stabilized sil ylene, stannylene complexes.