REACTIVITY OF CS2 TOWARDS THE ANION [MO(2)CP(2)(CO)(3)(PPH(2))(MU-ETA(2)-P-2)](-) - SYNTHESIS AND CHARACTERIZATION OF [MO(2)CP(2)(CO)(3)(MU-ETA(3)-PH(2)PC(H)SP2S)], A COMPLEX CONTAINING AN UNUSUAL CSP2S RING

Authors
DAVIES JE MAYS MJ RAITHBY PR SHIELDS GP TOMPKIN PK
Citation
Je. Davies et al., REACTIVITY OF CS2 TOWARDS THE ANION [MO(2)CP(2)(CO)(3)(PPH(2))(MU-ETA(2)-P-2)](-) - SYNTHESIS AND CHARACTERIZATION OF [MO(2)CP(2)(CO)(3)(MU-ETA(3)-PH(2)PC(H)SP2S)], A COMPLEX CONTAINING AN UNUSUAL CSP2S RING, Chemical communications, (17), 1996, pp. 2051-2052
Citations number
12
Categorie Soggetti
Chemistry
Journal title
Chemical communications → ACNP
ISSN journal
13597345
Issue
17
Year of publication
1996
Pages
2051 - 2052
Database
ISI
SICI code
1359-7345(1996):17<2051:ROCTTA>2.0.ZU;2-V
Abstract
The complex [Mo(2)Cp(2)(Co)(3)(PPh(2)H)(mu-eta(2)-P-2)] is deprotonate d at -78 degrees C by Bu(t)Li; subsequent addition of an excess of CS2 affords the novel complex [Mo(2)Cp(2)(CO)(3){mu-eta(3)-Ph(2)PC(H)SP2S }] in good to moderate yield.