NEW PHOSPHAZENE CHAINS AND LIGANDS IN COMPLEXES AND CLUSTERS

Authors
SLAWIN AMZ SMITH MB WOOLLINS JD
Citation
Amz. Slawin et al., NEW PHOSPHAZENE CHAINS AND LIGANDS IN COMPLEXES AND CLUSTERS, Chemical communications, (17), 1996, pp. 2095-2096
Citations number
9
Categorie Soggetti
Chemistry
Journal title
Chemical communications → ACNP
ISSN journal
13597345
Issue
17
Year of publication
1996
Pages
2095 - 2096
Database
ISI
SICI code
1359-7345(1996):17<2095:NPCALI>2.0.ZU;2-K
Abstract
Ph(2)PNP(Ph)(2)P(Ph)(2)NPPh(2) 1 is oxidised by S or Se to give Ph(2)P (E)NP(Ph)(2)P(Ph)(2)NP(E)Ph(2) (E = S 2, E = Se 3), endcapped by ClAu units or coordinated as a chelate with (CH3)(2)Pt; the diselenide 3 re acts with [Ru-3(CO)(12)] via oxidative addition of Se2- ions acid expu lsion of a PPh(2)(-) group to form a novel cluster containing the [Ph( 2)PNP(Ph)(2)NPPh(2)](-) ligand which is ligated by two terminal P atom s and by one N atom.