K-11[HSN3II((PW9O34)-O-VI)(2)]CENTER-DOT- 27H(2)O - SYNTHESIS AND STRUCTURE

Authors
BOTAR A BOTAR B GILI P MULLER A MEYER J BOGGE H SCHMIDTMANN M
Citation
A. Botar et al., K-11[HSN3II((PW9O34)-O-VI)(2)]CENTER-DOT- 27H(2)O - SYNTHESIS AND STRUCTURE, Zeitschrift fur anorganische und allgemeine Chemie, 622(9), 1996, pp. 1435-1440
Citations number
20
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Zeitschrift fur anorganische und allgemeine Chemie
ISSN journal
00442313 → ACNP
Volume
622
Issue
9
Year of publication
1996
Pages
1435 - 1440
Database
ISI
SICI code
0044-2313(1996)622:9<1435:K2-SAS>2.0.ZU;2-V
Abstract
K-11[HSn3II((PW9O34)-O-VI)(2)]. 27 H2O 1 can be synthesized in an ''on e-pot reaction'' from commercially obtainable educts (SnCl2; Na2HPO4 . 7 H2O, Na2WO4 . 2H(2)O) in high yields and has been characterized by elemental analysis, IR/Raman-, UV/Vis-spectroscopy as well as by X-ray crystal structure analysis. The example of 1 again demonstrates the v alidity of our working hypothesis, that polyoxometalates can be obtain ed by linking highly charged, transferable building blocks by cationic centres within the scope of an optimal charge control. For structural details see ''Inhaltsubersicht''.