AMMOXIMATION OF KETONES ON TITANIUM SILICALITE - A STUDY OF THE REACTION BY-PRODUCTS

Authors
MANTEGAZZA MA CESANA A PASTORI M
Citation
Ma. Mantegazza et al., AMMOXIMATION OF KETONES ON TITANIUM SILICALITE - A STUDY OF THE REACTION BY-PRODUCTS, Topics in catalysis, 3(3-4), 1996, pp. 327-335
Citations number
8
Categorie Soggetti
Chemistry Physical","Chemistry Applied
Journal title
Topics in catalysis → ACNP
ISSN journal
10225528
Volume
3
Issue
3-4
Year of publication
1996
Pages
327 - 335
Database
ISI
SICI code
1022-5528(1996)3:3-4<327:AOKOTS>2.0.ZU;2-P
Abstract
In the new EniChem process cyclohexanone oxime is directly synthesized by ammoximation of cyclohexanone with ammonia and hydrogen peroxide o n titanium silicalite catalyst. The ammoximation reaction is suitable for the synthesis of several oximes by reaction of the corresponding k etones with ammonia and hydrogen peroxide on titanium silicalite. New results on ketones ammoximation and on reaction byproducts are reporte d. The effect of some reaction parameters on the oxime yield and on by products formation is discussed.