A simple approximation for thermal diffusion in gas mixtures was recen
tly proposed [1]. This approximation was based upon relations valid fo
r rigid spheres. It is therefore appropriate for molecules with steep
repulsive potentials, but not for ionized species interacting via the
Coulomb potential. Here we formulate an analogous approximation for io
nized species and free electrons. The resulting thermal diffusion coef
ficients differ in sign from those for hard molecules.