Zf. Li et al., VISIBLE PHOTOLUMINESCENCE FROM HYDROGENATED AMORPHOUS-CARBON FILMS PREPARED BY PULSED-LASER ABLATION OF POLYMETHYL METHACRYLATE (PMMA), Applied physics A: Materials science & processing, 63(3), 1996, pp. 243-246
Visible photoluminescence (PL) has been observed from the hydrogenated
amorphous carbon (a-C:H) films prepared by ArF pulsed laser ablation
of polymethyl methacrylate (PMMA) in the presence of hydrogen gas (H-2
). With increasing hydrogen concentration the PL intensity increases a
nd the intensity maximum blue-shifted. The PL intensity also increases
after hours of light illumination, exhibiting a light soaking enhance
ment. Increasing the deposition temperature decreases the PL and incre
ases the ratio of sp(3)/sp(2) bonds.