N-PHENYL-2-(TRIPHENYLSTANNYLSELENO)BENZAMIDE AND 2-METHYLSELENO-N-PHENYLBENZAMIDE

Authors
FONG MC GABLE RW SCHIESSER CH
Citation
Mc. Fong et al., N-PHENYL-2-(TRIPHENYLSTANNYLSELENO)BENZAMIDE AND 2-METHYLSELENO-N-PHENYLBENZAMIDE, Acta crystallographica. Section C, Crystal structure communications, 52, 1996, pp. 1886-1889
Citations number
7
Categorie Soggetti
Crystallography
Journal title
Acta crystallographica. Section C, Crystal structure communications → ACNP
ISSN journal
01082701
Volume
52
Year of publication
1996
Part
8
Pages
1886 - 1889
Database
ISI
SICI code
0108-2701(1996)52:<1886:NA2>2.0.ZU;2-L
Abstract
The two independent molecules of N-phenyl-2-(triphenylstannylseleno)be nzamide, C31H25NOSeSn, differ significantly in the conformations of th e N-phenylbenzamide groups. For 2-methylseleno-N-phenylbenzamide, C14H 13NOSe, the N-phenylbenzamide group is oriented such that the O atom i s in close contact with the Se atom [Se ... O 2.829(2)Angstrom] and th e N atom is pointed away. In both compounds, the amide N atom is invol ved in hydrogen bonding with the O atom of an adjacent molecule, formi ng zigzag chains which lie along the a axis.