(THIOCYANATO-N)TRIS(TRIPHENYLPHOSPHINE)-SILVER(I) CHLOROFORM SOLVATE

Authors
OTHMAN AH FUN HK SIVAKUMAR K FARINA Y BABA I
Citation
Ah. Othman et al., (THIOCYANATO-N)TRIS(TRIPHENYLPHOSPHINE)-SILVER(I) CHLOROFORM SOLVATE, Acta crystallographica. Section C, Crystal structure communications, 52, 1996, pp. 1933-1935
Citations number
12
Categorie Soggetti
Crystallography
Journal title
Acta crystallographica. Section C, Crystal structure communications → ACNP
ISSN journal
01082701
Volume
52
Year of publication
1996
Part
8
Pages
1933 - 1935
Database
ISI
SICI code
0108-2701(1996)52:<1933:(CS>2.0.ZU;2-O
Abstract
Crystals of [Ag(NCS)(C18H15P)(3)].CHCl3 consist of discrete [Ag(PPh(3) )(3)(NCS)] molecules, in which the Ag atom is tetrahedrally surrounded by three P atoms of the PPh(3) groups and the N atom of the isothiocy anate ligand, and, and chloroform molecules. The coordination polyhedr on around the Ag atom is distorted with angles at Ag ranging from 102. 58(10) to 114.73(3)degrees. The Ag-N-C angle is 159.6(3)degrees.