THYLDITHIOCARBAMATO)(4-METHOXYPHENYL)TELLURIUM(IV)

Authors
HUSEBYE S ENGEBRETSEN T RUDD MD LINDEMAN SV
Citation
S. Husebye et al., THYLDITHIOCARBAMATO)(4-METHOXYPHENYL)TELLURIUM(IV), Acta crystallographica. Section C, Crystal structure communications, 52, 1996, pp. 2022-2024
Citations number
7
Categorie Soggetti
Crystallography
Journal title
Acta crystallographica. Section C, Crystal structure communications → ACNP
ISSN journal
01082701
Volume
52
Year of publication
1996
Part
8
Pages
2022 - 2024
Database
ISI
SICI code
0108-2701(1996)52:<2022:T>2.0.ZU;2-N
Abstract
The crystals of the Te-IV complex p-CH3OC6H4Te-(Et(2)NCS(2))(2)Br are isomorphous with those of the iodine and mixed iodine(bromine analogue s previously investigated. The structure is pentagonal bipyramidal at the Te atom with four S atoms [Te-S 2.618-2.721(1) Angstrom] and the B r atom [Te-Br 2.943 (1) Angstrom] in equatorial positions. The p-metho xyphenyl group is axial [Te-C 2.147(3) Angstrom]. The second axial pos ition is approached by a Br atom of a centrosymmetrically related comp lex [Te ... Br 3.423(1) Angstrom, C-Te ... Br 173.1 (1)degrees] so tha t the molecules are joined into centrosymmetric pairs by this weak sec ondary coordination.