2 N-ARYL-SUBSTITUTED SILYL CARBAMATES

Authors
BOCSKEI Z ROHONCZY J SZALAY R KNAUSZ D
Citation
Z. Bocskei et al., 2 N-ARYL-SUBSTITUTED SILYL CARBAMATES, Acta crystallographica. Section C, Crystal structure communications, 52, 1996, pp. 2063-2066
Citations number
13
Categorie Soggetti
Crystallography
Journal title
Acta crystallographica. Section C, Crystal structure communications → ACNP
ISSN journal
01082701
Volume
52
Year of publication
1996
Part
8
Pages
2063 - 2066
Database
ISI
SICI code
0108-2701(1996)52:<2063:2NSC>2.0.ZU;2-A
Abstract
Trimethylsilyl N-(4-bromophenyl)carbamate, C10H14BrNO2Si, and trimethy lsilyl N-tert-butyl-N-phenylcarbamate, C14H23NO2Si, are both important silylating agents. The structures of both molecules are dominated by a plane containing a remarkably large number of atoms. The planes are organized by delocalization around the carbamate moiety. A quasi-penta coordination of the Si atom in both compounds is also described.