2 14-MEMBERED MACROCYCLES WITH TRANS-TRANS AND TRANS-CIS DIENES - TRIMETHYL O[12.3.0]HEPTADECA-2,4-DIENE-7,7,14-TRICARBOXYLATE AND TRIMETHYL O[12.3.0]HEPTADECA-2,4-DIENE-7,7,14-TRICARBOXYLATE

Authors
DROUIN M COUTURIER M CREVISY C DORY YL DESLONGCHAMPS P
Citation
M. Drouin et al., 2 14-MEMBERED MACROCYCLES WITH TRANS-TRANS AND TRANS-CIS DIENES - TRIMETHYL O[12.3.0]HEPTADECA-2,4-DIENE-7,7,14-TRICARBOXYLATE AND TRIMETHYL O[12.3.0]HEPTADECA-2,4-DIENE-7,7,14-TRICARBOXYLATE, Acta crystallographica. Section C, Crystal structure communications, 52, 1996, pp. 2084-2087
Citations number
15
Categorie Soggetti
Crystallography
Journal title
Acta crystallographica. Section C, Crystal structure communications → ACNP
ISSN journal
01082701
Volume
52
Year of publication
1996
Part
8
Pages
2084 - 2087
Database
ISI
SICI code
0108-2701(1996)52:<2084:21MWTA>2.0.ZU;2-U
Abstract
Two new isomeric 14-membered ring compounds, C23H30O8, were synthesize d based on Michael addition macrocyclization, which leads to completel y controlled diene,geometries, trans-trans and trans-cis. The crystal structures show the respective trans-trans and trans-cis diene geometr ies and their corresponding cis and trans ring junctions.