EFFICIENT TRANSFORMATIONS OF ALDEHYDES AND KETONES INTO ONE-CARBON HOMOLOGATED CARBOXYLIC-ACIDS

Authors
KATRITZKY AR TOADER D XIE LH
Citation
Ar. Katritzky et al., EFFICIENT TRANSFORMATIONS OF ALDEHYDES AND KETONES INTO ONE-CARBON HOMOLOGATED CARBOXYLIC-ACIDS, Synthesis, (12), 1996, pp. 1425
Citations number
36
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Synthesis → ACNP
ISSN journal
00397881
Issue
12
Year of publication
1996
Database
ISI
SICI code
0039-7881(1996):12<1425:ETOAAK>2.0.ZU;2-7
Abstract
Peterson olefination of aldehydes and ketones with trimethylsilyl(meth oxy)(benzo triazol-1-yl)methyl anion 6 afforded 1 -(benzo-triazol-1-yl )-1-methoxyalk-1-enes 7 which were treated without isolation with zinc bromide and hydrochloric acid, to yield the corresponding one-carbon homologated carboxylic acids 4 in good overall yields.