STRUCTURE-STABILITY RELATIONSHIPS IN UNSATURATED SULFUR-COMPOUNDS .7.STABILIZATION ENERGIES DUE TO ALKYL-GROUPS ATTACHED TO THE ALPHA-CARBON AND BETA-CARBON OF VINYL SULFONES

Authors
KIMMELMA R PELTOLA T
Citation
R. Kimmelma et T. Peltola, STRUCTURE-STABILITY RELATIONSHIPS IN UNSATURATED SULFUR-COMPOUNDS .7.STABILIZATION ENERGIES DUE TO ALKYL-GROUPS ATTACHED TO THE ALPHA-CARBON AND BETA-CARBON OF VINYL SULFONES, Acta chemica Scandinavica, 50(9), 1996, pp. 783-787
Citations number
25
Categorie Soggetti
Chemistry,Biology
Journal title
Acta chemica Scandinavica → ACNP
ISSN journal
0904213X
Volume
50
Issue
9
Year of publication
1996
Pages
783 - 787
Database
ISI
SICI code
0904-213X(1996)50:9<783:SRIUS.>2.0.ZU;2-T
Abstract
According to thermodynamic results a methyl or ethyl group attached to the beta carbon of a vinyl sulfone causes a stabilization of ca. 13 k J mol(-1). The corresponding stabilization caused by an a alkyl group is ca. 10 kJ mol(-1).