HALOGEN EXCHANGE IN SUBSTITUTED ALLYLTIN HALIDES STUDIED BY 2D NMR EXSY AS A TOOL TO ASSESS REACTIVITY

Authors
FOUQUET E ROULET T WILLEM R PIANET I
Citation
E. Fouquet et al., HALOGEN EXCHANGE IN SUBSTITUTED ALLYLTIN HALIDES STUDIED BY 2D NMR EXSY AS A TOOL TO ASSESS REACTIVITY, Journal of organometallic chemistry, 524(1-2), 1996, pp. 103-106
Citations number
19
Categorie Soggetti
Chemistry Inorganic & Nuclear","Chemistry Inorganic & Nuclear
Journal title
Journal of organometallic chemistry → ACNP
ISSN journal
0022328X
Volume
524
Issue
1-2
Year of publication
1996
Pages
103 - 106
Database
ISI
SICI code
0022-328X(1996)524:1-2<103:HEISAH>2.0.ZU;2-R
Abstract
The halogen exchange between two monoallyltin compounds has been inves tigated by Sn-119 2D NMR EXSY. It is demonstrated that the slower halo gen exchange observed in the allylbisN,N(bistrimethylsilyl)aminotin ha lide compared with the allyltin trihalides can be correlated with the dramatic change in reactivity of these compounds in allyl radical tran sfer.