SYNTHESIS AND COORDINATION CHEMISTRY OF THE TETHERED BIS(CYCLOPENTADIENYL)-PHOSPHINE LIGAND PRECURSOR PPH(CH2CH2C5H5)(2) - X-RAY STRUCTURE OF TRANS-PDCL2[PPH(CH2CH2-ETA(5)-C5H4)(2)FE](2)

Authors
CURNOW OJ HUTTNER G SMAIL SJ TURNBULL MM
Citation
Oj. Curnow et al., SYNTHESIS AND COORDINATION CHEMISTRY OF THE TETHERED BIS(CYCLOPENTADIENYL)-PHOSPHINE LIGAND PRECURSOR PPH(CH2CH2C5H5)(2) - X-RAY STRUCTURE OF TRANS-PDCL2[PPH(CH2CH2-ETA(5)-C5H4)(2)FE](2), Journal of organometallic chemistry, 524(1-2), 1996, pp. 267-270
Citations number
20
Categorie Soggetti
Chemistry Inorganic & Nuclear","Chemistry Inorganic & Nuclear
Journal title
Journal of organometallic chemistry → ACNP
ISSN journal
0022328X
Volume
524
Issue
1-2
Year of publication
1996
Pages
267 - 270
Database
ISI
SICI code
0022-328X(1996)524:1-2<267:SACCOT>2.0.ZU;2-9
Abstract
The preparation of the tethered bis(cyclopentadienyl)-phosphine compou nd bis(2-cyclopentadienylethyl)phenylphosphine 1 from phenylphosphine, n-butyllithium and spiro[2,4]hepta-4,6-diene is described. The synthe sis of the ferrocene complex PPh(CH2CH2-eta(5)-C5H4)(2)Fe 2 from 1 and the synthesis of the heterobimetallic Pd-Fe complex trans-PdCl2[PPh(C H2CH2-eta(5)-C5H4)(2)Fe](2) 3 from 2, along with its X-ray structure, is also described.