MECHANISM OF OLEFIN HYDROFORMYLATION IN THE PRESENCE OF A COBALT CARBONYL-PYRIDINE COMPLEX AS A CATALYST PRECURSOR

Authors
VIGRANENKO YT RYBAKOV VA KASHINA VV TARASOV BP
Citation
Yt. Vigranenko et al., MECHANISM OF OLEFIN HYDROFORMYLATION IN THE PRESENCE OF A COBALT CARBONYL-PYRIDINE COMPLEX AS A CATALYST PRECURSOR, Kinetics and catalysis, 37(4), 1996, pp. 524-527
Citations number
14
Categorie Soggetti
Chemistry Physical
Journal title
Kinetics and catalysis → ACNP
ISSN journal
00231584
Volume
37
Issue
4
Year of publication
1996
Pages
524 - 527
Database
ISI
SICI code
0023-1584(1996)37:4<524:MOOHIT>2.0.ZU;2-O
Abstract
Based on IR spectroscopic studies of the reaction products, a mechanis m for olefin hydroformylation in the presence of a cobalt carbonyl-pyr idine complex as a catalyst precursor was proposed. The equilibrium co nstants of elementary steps and the rate constant of the rate-determin ing step at 140 degrees C were calculated.