HYBRID INORGANIC-ORGANOMETALLIC COMPOUNDS WITH GALLIUM-GALLIUM BONDS

Authors
COWLEY AH DECKEN A OLAZABAL CA
Citation
Ah. Cowley et al., HYBRID INORGANIC-ORGANOMETALLIC COMPOUNDS WITH GALLIUM-GALLIUM BONDS, Journal of organometallic chemistry, 524(1-2), 1996, pp. 271-273
Citations number
9
Categorie Soggetti
Chemistry Inorganic & Nuclear","Chemistry Inorganic & Nuclear
Journal title
Journal of organometallic chemistry → ACNP
ISSN journal
0022328X
Volume
524
Issue
1-2
Year of publication
1996
Pages
271 - 273
Database
ISI
SICI code
0022-328X(1996)524:1-2<271:HICWGB>2.0.ZU;2-1
Abstract
The first examples of digallium compounds that feature both organo and halo substituents, [Li(THF)(4)][Ar'(Cl)GaGaCl3] (1) and Ar'(Cl)GaGa(C l)Ar' (2), have been prepared by reaction of Ga2Cl4 . 2 dioxane with L iAr' (Ar' = 2,4,6 -(1)Bu(3)C(6)H(2)). The Ga2Cl2 skeleton of 2 is plan ar with a dihedral angle of 180 degrees.