THE MOLECULAR-STRUCTURE OF TETRAKIS(TRIMETHYLSTANNYL)METHANE BY GAS ELECTRON-DIFFRACTION

Authors
HAALAND A SOKOLOV VI VOLDEN HV KUHNER S WEIDLEIN J
Citation
A. Haaland et al., THE MOLECULAR-STRUCTURE OF TETRAKIS(TRIMETHYLSTANNYL)METHANE BY GAS ELECTRON-DIFFRACTION, Journal of organometallic chemistry, 524(1-2), 1996, pp. 285-287
Citations number
12
Categorie Soggetti
Chemistry Inorganic & Nuclear","Chemistry Inorganic & Nuclear
Journal title
Journal of organometallic chemistry → ACNP
ISSN journal
0022328X
Volume
524
Issue
1-2
Year of publication
1996
Pages
285 - 287
Database
ISI
SICI code
0022-328X(1996)524:1-2<285:TMOTBG>2.0.ZU;2-V
Abstract
The gas phase electron diffraction data of C(SnMe(3))(4) recorded wit h a nozzle temperature of about 120 degrees C are consistent with a mo lecular model of T symmetry; the bond distances (r(a)) are C-Sn = 217 .7(3), Sn-C = 216.2(4), and C-H = 112.2(6) pm; the valence angles angl e CSnC = 112.3(4)degrees and angle SnCH = 111.5(6)degrees.