The frequency response spectra of propane in silicalite-l were measure
d at equilibrium pressures of 0.5-8.0 Torr and temperatures of 303-363
K and analysed by non-isothermal diffusion, two independent diffusion
processes, and single-diffusion models. The first model is physically
feasible for the explanation of the bimodal FR behaviour of this syst
em, but the heat effect can be eliminated by reducing the coverage in
the zeolite. Compared with propane, the bimodal form of the frequency
response curves of p-xylene in silicalite-1 is attributed to two diffu
sion processes occurring separately in the sinusoidal and straight cha
nnels of the sorbent. The intracrystalline self-diffusion coefficient
of propane in silicalite-1 determined in the present work is of the or
der of 10(-9) m(2)s(-1) and decreases with increasing concentration of
the adsorbate in the zeolite. This result is consistent with PFG NMR
and previous FR studies.