V. Raineri et al., ATOMIC-FORCE MICROSCOPY ON SIO2 LAYERS GROWN ON GE IMPLANTED SILICON, Nuclear instruments & methods in physics research. Section B, Beam interactions with materials and atoms, 116(1-4), 1996, pp. 482-485
GexSi1-x layers were obtained by high dose Ge implants in (100) silico
n substrates followed by solid phase epitaxy. Ge was implanted at seve
ral energies in the 35-140 keV range and for different doses ranging f
rom 3 x 10(15)/cm(2) to 3 x 10(16)/cm(2). Atomic force microscopy show
s that surface roughness after oxidation is much larger in GexSi1-x sa
mples than in silicon. Rutherford backscattering spectrometry reveals
that the oxide layer formed on the GexSi1-x is essentially composed by
SiO2, while Ge piles up at the SiO2/GexSi1-x interface. Ge accumulati
on is due to the selective oxidation of Si with respect to Ge, and pro
duces Ge islands at the SiO2/GexSi1-x interface and the anomalous grow
th of the SiO2 layer. These effects are enhanced when thicker oxides a
re grown, or larger Ge doses are implanted, while they are reduced for
implants at higher energies.