SYNTHESIS, ISOMERIZATION AND DIELS-ALDER REACTIONS OF (5S)-5-PHENYL-3,4-DEHYDROMORPHOLIN-2-ONE

Authors
AGER D COOPER N COX GG GARROHELION F HARWOOD LM
Citation
D. Ager et al., SYNTHESIS, ISOMERIZATION AND DIELS-ALDER REACTIONS OF (5S)-5-PHENYL-3,4-DEHYDROMORPHOLIN-2-ONE, Tetrahedron : asymmetry, 7(9), 1996, pp. 2563-2566
Citations number
19
Categorie Soggetti
Chemistry Inorganic & Nuclear","Chemistry Inorganic & Nuclear","Chemistry Physical
Journal title
Tetrahedron : asymmetry → ACNP
ISSN journal
09574166
Volume
7
Issue
9
Year of publication
1996
Pages
2563 - 2566
Database
ISI
SICI code
0957-4166(1996)7:9<2563:SIADRO>2.0.ZU;2-D
Abstract
(5S)-5-Phenyl-3,4-dehydromorpholin-2-one [(5S)-5-phenyl-5,6-dihydro-2H -1,4-oxazin-2-one] 2a is prepared by a one-pot bromination / dehydrobr omination of (SS)-5-phenyl morpholin-2-one and undergoes regio- and di astereocontrolled catalysed Diels-Alder reactions. Copyright (C) 1996 Elsevier Science Ltd