CHIRAL LIGANDS CONTAINING HETEROATOMS .15. CYCLIC BETA-AMINO ALCOHOLSAS CHIRAL INDUCTORS FOR ENANTIOSELECTIVE REDUCTIONS OF KETONES

Authors
FALORNI M COLLU C GIACOMELLI G
Citation
M. Falorni et al., CHIRAL LIGANDS CONTAINING HETEROATOMS .15. CYCLIC BETA-AMINO ALCOHOLSAS CHIRAL INDUCTORS FOR ENANTIOSELECTIVE REDUCTIONS OF KETONES, Tetrahedron : asymmetry, 7(9), 1996, pp. 2739-2742
Citations number
10
Categorie Soggetti
Chemistry Inorganic & Nuclear","Chemistry Inorganic & Nuclear","Chemistry Physical
Journal title
Tetrahedron : asymmetry → ACNP
ISSN journal
09574166
Volume
7
Issue
9
Year of publication
1996
Pages
2739 - 2742
Database
ISI
SICI code
0957-4166(1996)7:9<2739:CLCH.C>2.0.ZU;2-Y
Abstract
Cyclic beta-amino alcohols 1-4 derived from natural alpha-amino acids were used as chiral ligands in oxazaborolidine reduction of ketones. T he processes were carried out in the presence of various achiral terti ary amine: better resuts are achieved by N,N-diethylaniline. Copyright (C) 1996 Published by Elsevier Science Ltd