SYNTHESIS, CHARACTERIZATION, AND BONDING OF 2 NEW HETEROPOLYCHALCOGENIDES - ALPHA-CSCU(SXSE4-X) AND CSCU(SXSE6-X)

The Cs-Cu-Q (Q = S, Se) system has been investigated using copper meta l, cesium chloride, and alkali-metal polychalcogenide salts under mild hydrothermal reaction conditions. Heteropolychalcogenide salts and mi xtures of known polysulfide and polyselenide salts have been used as r eagents. The reaction products contain the alpha-CsCuQ(4) and CsCuQ(6) structures. The alpha-CsCuQ(4) phase exhibits a smooth transition in lattice parameters from the pure sulfur to the pure selenium phases, b ased on Vegard's law. The CsCuQ(6) phase has been prepared as the pure sulfur analog and a selenium rich analog. The single-crystal structur es of the disordered compounds alpha-CsCuS2-Se-2 (P2(1)2(1)2(1), Z = 4 , a = 5.439(1) Angstrom, b = 8.878(2) Angstrom, c = 13.762(4) Angstrom ) and CsCuS1.6Se4.4 (P (1) over bar, Z = 2, a = 11.253(4) Angstrom, b = 11.585(2) Angstrom, c = 7.211(2) Angstrom, alpha = 92.93 degrees, be ta = 100.94 degrees, gamma = 74.51 degrees) have been solved using a c orrelated-site occupancy model. These disordered structures display a polychalcogenide geometry in which the sulfur atoms prefer positions t hat are bound to copper. The optical absorption spectra of these mater ials have been investigated. The optical band gap varies as a function of the sulfur-selenium ratio. Extended Huckel crystal orbital calcula tions have been performed to investigate the electronic structure and bonding in these compounds in an attempt to explain the site distribut ion of sulfur and selenium.