DEVELOPMENT OF A MODIFIED BROMLEYS METHODOLOGY (MBM) FOR THE ESTIMATION OF IONIC MEDIA EFFECTS ON SOLUTION EQUILIBRIA .2. CORRELATION OF THE MOLAR AND MOLAL INTERACTION PARAMETERS WITH THE CHARGE AND CRYSTAL RADII OF THE IONS

Authors
BORGE G ETXEBARRIA N FERNANDEZ LA OLAZABAL MA MADARIAGA JM
Citation
G. Borge et al., DEVELOPMENT OF A MODIFIED BROMLEYS METHODOLOGY (MBM) FOR THE ESTIMATION OF IONIC MEDIA EFFECTS ON SOLUTION EQUILIBRIA .2. CORRELATION OF THE MOLAR AND MOLAL INTERACTION PARAMETERS WITH THE CHARGE AND CRYSTAL RADII OF THE IONS, Fluid phase equilibria, 121(1-2), 1996, pp. 99-109
Citations number
10
Categorie Soggetti
Engineering, Chemical","Chemistry Physical
Journal title
Fluid phase equilibria → ACNP
ISSN journal
03783812
Volume
121
Issue
1-2
Year of publication
1996
Pages
99 - 109
Database
ISI
SICI code
0378-3812(1996)121:1-2<99:DOAMBM>2.0.ZU;2-O
Abstract
The interaction parameters of strong electrolytes obtained for both th e molar and molal scales using the Modified Bromley's Methodology (MBM ) have been correlated with the ionic charge and individual crystal ra dius of each ion. The correlation function for each ion with opposite counterions is a straight line centered in the water radius value (1.3 9 X 10(-10) m). These correlations allow the prediction of values of u nknown interaction parameters of a cation with several anions even if only one interaction parameter of the cation with a given anion is kno wn.