BINAS - SYNTHESIS AND USE OF A NEW LIGAND FOR PROPYLENE HYDROFORMYLATION

Authors
BAHRMANN H BERGRATH K KLEINER HJ LAPPE P NAUMANN C PETERS D REGNAT D
Citation
H. Bahrmann et al., BINAS - SYNTHESIS AND USE OF A NEW LIGAND FOR PROPYLENE HYDROFORMYLATION, Journal of organometallic chemistry, 520(1-2), 1996, pp. 97-100
Citations number
26
Categorie Soggetti
Chemistry Inorganic & Nuclear","Chemistry Inorganic & Nuclear
Journal title
Journal of organometallic chemistry → ACNP
ISSN journal
0022328X
Volume
520
Issue
1-2
Year of publication
1996
Pages
97 - 100
Database
ISI
SICI code
0022-328X(1996)520:1-2<97:B-SAUO>2.0.ZU;2-#
Abstract
BINAS is a new, very efficient ligand for propylene hydroformylation. BINAS is made by me sulfonation of NAPHOS. Different synthetic routes to NAPHOS are discussed. A new two step synthesis starting from 2,2'-b is(bromomethyl)-1,1'-binaphthyl is described.