LINKED AMIDO-INDENYL COMPLEXES OF TITANIUM

Authors
AMOR F OKUDA J
Citation
F. Amor et J. Okuda, LINKED AMIDO-INDENYL COMPLEXES OF TITANIUM, Journal of organometallic chemistry, 520(1-2), 1996, pp. 245-248
Citations number
21
Categorie Soggetti
Chemistry Inorganic & Nuclear","Chemistry Inorganic & Nuclear
Journal title
Journal of organometallic chemistry → ACNP
ISSN journal
0022328X
Volume
520
Issue
1-2
Year of publication
1996
Pages
245 - 248
Database
ISI
SICI code
0022-328X(1996)520:1-2<245:LACOT>2.0.ZU;2-S
Abstract
Titanium complexes Ti(eta(5):eta(1)-C(9)H(6)SiMe(2)NCMe(3))X(2) (X = C l, Me, CH(2)SiMe(3), CH(2)Ph) containing the tert-amido-functionalized indenyl ligand C(9)H(6)SiMe(2)NCMe(3) have been synthesized by the re action of the dilithium derivative Li-2[C(9)H(6)SiMe(2)NCMe(3)] with T iCl3 (THF)(3) followed by oxidation or by the alkylation of the dichlo ro derivative. Unexpectedly, the reaction of C9H6(SiMe(3))(SiMe(2)Cl) with TiCl4 does not give Ti(eta(5)-C(9)H(6)SiMe(2)Cl)Cl-3.