INTERMOLECULAR ADDITIONS OF ALPHA-BORYL RADICALS

Citation
Ra. Batey et al., INTERMOLECULAR ADDITIONS OF ALPHA-BORYL RADICALS, Tetrahedron letters, 37(38), 1996, pp. 6847-6850
Citations number
25
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
ISSN journal
00404039
Volume
37
Issue
38
Year of publication
1996
Pages
6847 - 6850
Database
ISI
SICI code
0040-4039(1996)37:38<6847:IAOAR>2.0.ZU;2-J
Abstract
The utility of alpha-boryl radicals 1 in intermolecular addition proce sses is described. Boronic ester substituted radicals are shown to add to both electron deficient and electron rich radical traps, and give high yields of homoallylboronic esters in radical allylation reactions . Copyright (C) 1996 Elsevier Science Ltd