SYNTHETIC STUDIES ON REVEROMYCIN-A - STEREOSELECTIVE SYNTHESIS OF THESPIROKETAL SYSTEM

Authors
SHIMIZU T KOBAYASHI R OSAKO K OSADA H NAKATA T
Citation
T. Shimizu et al., SYNTHETIC STUDIES ON REVEROMYCIN-A - STEREOSELECTIVE SYNTHESIS OF THESPIROKETAL SYSTEM, Tetrahedron letters, 37(37), 1996, pp. 6755-6758
Citations number
12
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Tetrahedron letters → ACNP
ISSN journal
00404039
Volume
37
Issue
37
Year of publication
1996
Pages
6755 - 6758
Database
ISI
SICI code
0040-4039(1996)37:37<6755:SSOR-S>2.0.ZU;2-X
Abstract
The 6,6-spiroketal system of reveromycin A (1), corresponding to the C -9-C-20 part, was stereoselectively synthesized and the absolute confi guration at C-11, C-12, C-15, C-18 and C-19 of 1 was confirmed by the synthesis of the 5,6-spiroketal derivative degradated from 1. Copyrigh t (C) 1996 Elsevier Science Ltd