STEREOSELECTIVE NUCLEOPHILIC EPOXIDATION OF HYDROXY VINYL SULFOXIDE DERIVATIVES

Authors
DELAPRADILLA RF MANZANO P PRIEGO J VISO A MARTINEZRIPOLL M RODRIGUEZ A
Citation
Rf. Delapradilla et al., STEREOSELECTIVE NUCLEOPHILIC EPOXIDATION OF HYDROXY VINYL SULFOXIDE DERIVATIVES, Tetrahedron letters, 37(37), 1996, pp. 6793-6796
Citations number
11
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Tetrahedron letters → ACNP
ISSN journal
00404039
Volume
37
Issue
37
Year of publication
1996
Pages
6793 - 6796
Database
ISI
SICI code
0040-4039(1996)37:37<6793:SNEOHV>2.0.ZU;2-U
Abstract
The diastereoselectivity of the nucleophilic epoxidation of vinyl sulf oxides bearing oxygenated substituents at allylic positions, 1-4, with MOO-t-Bu (M = Na, K) is primarily controlled by the chiral sulfur ato m. Copyright (C) 1996 Elsevier Science Ltd