SYNTHESES OF 6-MEMBERED AND 7-MEMBERED NITROGEN-HETEROCYCLES FROM CYCLIC AMINO PHOSPHNIUM SALTS

Citation
T. Sakai et al., SYNTHESES OF 6-MEMBERED AND 7-MEMBERED NITROGEN-HETEROCYCLES FROM CYCLIC AMINO PHOSPHNIUM SALTS, Heterocyclic communications, 2(3), 1996, pp. 233-239
Citations number
9
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
ISSN journal
07930283
Volume
2
Issue
3
Year of publication
1996
Pages
233 - 239
Database
ISI
SICI code
0793-0283(1996)2:3<233:SO6A7N>2.0.ZU;2-R
Abstract
The cyclic aza-ylides, 2a, b, that are generated from 6- or 5-membered cyclic amino phosphonium salts, 1a, b, can react with various carbony l compounds. The acyclic imine derivatives were obtained by the reacti on of these cyclic aza-ylides with benzils, and these imine derivative s were treated with LDA to produce the tetrahydropyridine or tetrahydr oazepine derivatives.